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Gold ΔMass ✓ Hydroxylation

LBO

Arabidopsis thaliana

Brassicaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
methyl carlactonoate
PubChem ↗ COC(=O)C(/C=C/C1=C(C)CCCC1(C)C)=C/O[C@H]1C=C(C)C(=O)O1
LBO
ΔMass: +15.9949 Da hydroxylation(+15.9949)
Product
1'-hydroxymethyl carlactonoate
PubChem ↗ CC1=C[C@H](O/C=C(\C=C\C2=C(C)CCCC2(C)C)C(=O)OCO)OC1=O

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; LBO converts MeCLA to 1'-HO-MeCLA; confirmed by deuterated feeding experiments.

Reaction & quality gates

Mechanism
Hydroxylation (+15.99 Da)
Evidence type
In vitro
Confidence
High
Data tier
Gold
Latin binomial + experiment + dual SMILES + ΔMass pass
Substrate class
Organic acids
Product class
Organic acids

Literature & public identifiers

PubMed
PMID:32399509 ↗
DOI
10.1002/pld3.219 ↗
UniProt
Q9LIF4 ↗
GenBank
NCBI TaxID
3702 ↗

Hydroxyl carlactone derivatives are predominant strigolactones in <i>Arabidopsis</i>.