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Silver mismatch Oxidation

CYP82G1

Arabidopsis thaliana

Brassicaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
(E,E)-geranyllinalool
PubChem ↗ CC(=CCC/C(=C/CC/C(=C/CCC(C)(C=C)O)/C)/C)C
CYP82G1
ΔMass: -72.0575 Da mismatch
Product
(E,E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene (TMTT)
PubChem ↗ CC(=CCC/C(=C/CC/C(=C/C=C)/C)/C)C

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; CYP82G1敲除突变体（GK377A01）经alamethicin处理后不产生TMTT，互补表达恢复TMTT生成。

Reaction & quality gates

Mechanism
Oxidation
Evidence type
In vivo
Confidence
High
Data tier
Silver
mass=mismatch
Substrate class
Terpenoids
Product class
Other

Literature & public identifiers

PubMed
PMID:21088219 ↗
DOI
10.1073/pnas.1009975107 ↗
UniProt
Q9LSF8 ↗
GenBank
—
NCBI TaxID
3702 ↗

Herbivore-induced and floral homoterpene volatiles are biosynthesized by a single P450 enzyme (CYP82G1) in Arabidopsis.

Other reactions by this enzyme

(E,E)-geranyllinalool → (E,E)-4,8,12-trimethyltrideca-1,3,7,11-…
Silver Oxidation mismatch
(E)-nerolidol → (E)-4,8-dimethyl-1,3,7-nonatriene (DMNT)
Silver Oxidation mismatch
(E)-nerolidol → (E)-4,8-dimethyl-1,3,7-nonatriene (DMNT)
Silver Oxidation mismatch
(E,E)-geranyllinalool → (E,E)-4,8,12-trimethyl-1,3,7,11-trideca…
Silver Oxidation no_smiles
E-nerolidol → 4,8-dimethylnona-1,3,7-triene (DMNT)
Silver Oxidation mismatch