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Quarantine mismatch Cyclization

GbTPS1

Gossypium barbadense

Malvaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
neryl diphosphate
PubChem ↗ CC(=CCC/C(=C\COP(=O)(O)OP(=O)(O)O)/C)C
GbTPS1
ΔMass: -177.9432 Da mismatch
Product
limonene
PubChem ↗ CC1=CCC(CC1)C(=C)C

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ization; ization; Recombinant GbTPS1 catalyzed NPP to produce limonene as single product.

Reaction & quality gates

Mechanism
Cyclization
Evidence type
In vitro
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Terpenoids

Literature & public identifiers

PubMed
PMID:35909734 ↗
DOI
10.3389/fpls.2022.898541 ↗
UniProt
GenBank
NCBI TaxID
3634 ↗

Characterization of a Novel Insect-Induced Sesquiterpene Synthase GbTPS1 Based on the Transcriptome of <i>Gossypium barbadense</i> Feeding by Cotton Bollworm.