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Quarantine no_smiles Cyclization

TgTPS6

Tectona grandis

Lamiaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
ent-copalyl diphosphate
PubChem ↗ C/C(=C\COP(=O)(O)OP(=O)(O)O)/CC[C@@H]1C(=C)CC[C@H]2[C@]1(CCCC2(…
TgTPS6
ΔMass: no_smiles Missing dual SMILES or RDKit not validated
Product
ent-copalyldiphosphate
PubChem ↗ Crowdsource product structure

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ization; ization; Transient expression in Nicotiana benthamiana; catalyzes formation of ent-copalyldiphosphate.

Reaction & quality gates

Mechanism
Cyclization
Evidence type
In vivo
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:30698701 ↗
DOI
10.1093/gigascience/giz005 ↗
UniProt
GenBank
NCBI TaxID
41396 ↗

A chromosomal-scale genome assembly of Tectona grandis reveals the importance of tandem gene duplication and enables discovery of genes in natural product biosynthetic pathways.