Silver
no_smiles
Oxidation
Substrate reaction site
Product reaction site
MCS substructure diff highlighting · RDKit atom mapping
Substrate
19E-geissoschizine
PubChem ↗
C/C=C\1/CN2CCC3=C([C@@H]2C[C@@H]1/C(=C/O)/C(=O)OC)NC4=CC=CC=C34
GO
ΔMass: no_smiles
Missing dual SMILES or RDKit not validated
Evidence trail
Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.
Source text excerpt ation; ation; TiGO expressed in yeast microsomes; conversion confirmed by LC-MS and observation of akuammicine and oxyindole intermediate.
Reaction & quality gates
- Mechanism
- Oxidation
- Evidence type
- In vitro
- Confidence
- High
- Data tier
- Silver
mass=no_smiles; incomplete_SMILES - Substrate class
- Other
- Product class
- Other
Literature & public identifiers
- PubMed
- PMID:41478566 ↗
- DOI
- 10.1016/j.jbc.2025.111120 ↗
- UniProt
- PX547879 ↗
- GenBank
- PX547879 ↗
- NCBI TaxID
- 141617 ↗
Conserved early steps of stemmadenine biosynthesis.