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Quarantine mismatch Glycosylation

UGT87Y1

Eucalyptus camphora

Myrtaceae

Substrate reaction site Product reaction site MCS substructure diff highlighting · RDKit atom mapping
Substrate
mandelonitrile
PubChem ↗ C1=CC=C(C=C1)C(C#N)O
UGT87Y1
ΔMass: +162.0528 Da mismatch
Product
prunasin
PubChem ↗ C1=CC=C(C=C1)[C@H](C#N)O[C@H]2[C@@H]([C@H]([C@@H]([C@H](O2)CO)O…

Evidence trail

Excerpts are machine-extracted plain text for biochemical provenance. Follow DOI / PubMed links for the primary literature; publisher figures and PDF images are not displayed here.

Source text excerpt ation; ation; Purified recombinant UGT87Y1 from E. camphora/E. yarraensis glucosylated mandelonitrile in vitro using 14C-UDP-glucose; also confirmed by transient expression in N. benthamiana.

Reaction & quality gates

Mechanism
Glycosylation
Evidence type
In vitro
Confidence
High
Data tier
Quarantine
non-CYP auxiliary enzyme (pathway partner, not cytochrome P450)
Substrate class
Other
Product class
Other

Literature & public identifiers

PubMed
PMID:36305250 ↗
DOI
10.1111/nph.18581 ↗
UniProt
GenBank
NCBI TaxID
1711200 ↗

Recruitment of distinct UDP-glycosyltransferase families demonstrates dynamic evolution of chemical defense within Eucalyptus L'Hér.